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Chemo- and Stereoselective Polymerization of Polar Divinyl Monomers by Rare-Earth Complexes

期刊: MACROMOLECULES, 2021; 54 (7)

Chemoselective polymerization of divinyl monomers is a promising strategy to access functional polymers via postpolymerization, which however, encount......

Transformation from Rod-Like to Diamond-Like Micelles by Thermally Induced Nucleation Self-Assembly

期刊: MACROMOLECULES, 2021; 54 (11)

Precisely controlled organic one-dimensional (1D) and two-dimensional (2D) materials with unique optoelectronic properties have attracted wide interes......

Combination of the Photoinduced Atom Transfer Radical Addition Reaction and Living Cationic Polymerization: A Latent Initiator Strategy toward Tailoring Polymer Molecular Weight Distributions

期刊: MACROMOLECULES, 2021; 54 (13)

The polymer molecular weight distribution (MWD) has a vital impact on material properties. Here, we presented a convenient approach for controlling th......

Low-Concentration Salt Solution Changes the Interfacial Molecular Behavior of Polyelectrolyte Brushes

期刊: MACROMOLECULES, 2021; 54 (13)

The interfacial molecular structures of polyelectrolyte brushes grafted on solid substrates are generally influenced by the electrostatic interaction ......

Self-Seeding of Oligo(p-phenylenevinylene)-b-poly(2-vinylpyridine) Micelles: Effect of Metal Ions

期刊: MACROMOLECULES, 2021; 54 (14)

Self-seeding is a useful protocol for generating elongated fiberlike block copolymer micelles of uniform length starting with micelle fragments obtain......

Molecular Orientations at Buried Conducting Polymer/Graphene Interfaces

期刊: MACROMOLECULES, 2021; 54 (9)

Graphene and semiconducting polymers have been extensively researched for use in many microelectronic devices. For both devices with layered structure......

Formation of Stacked Three-Dimensional Polymer "Single Crystals"

期刊: MACROMOLECULES, 2021; 54 (10)

Stacks of crystalline lamellae all having a uniquely oriented hexagonal shape, referred to as "3D (three-dimensional) single crystals", were obtained ......

Topological Effect on Macromonomer Polymerization

期刊: MACROMOLECULES, 2021; 54 (13)

The larger size of macromonomers compared to that of regular monomers brings new synthetic challenges and calls for an in-depth investigation on polym......

Aptamer-Conjugated Micelles for Targeted Photodynamic Therapy Via Photoinitiated Polymerization-Induced Self-Assembly

期刊: MACROMOLECULES, 2021; 54 (16)

Here, we report photoinitiated polymerization-induced self-assembly (photo-PISA) mediated by Rose Bengal methacrylate (RBMA) to reproducibly construct......

Utilization of Poor RAFT Control in Heterogeneous RAFT Polymerization

期刊: MACROMOLECULES, 2021; 54 (10)

Heterogeneous reversible addition-fragmentation chain transfer (RAFT) polymerization exhibits considerable promise in polymer and colloid synthesis. D......

Electrostatic Control of the Three-Dimensional Confined Assembly of Charged Block Copolymers in Emulsion Droplets

期刊: MACROMOLECULES, 2021; 54 (12)

Understanding the microphase separation of charged block copolymers (BCPs) is very important for the development of functional materials with tunable ......

Superlubricity Achieved with Zwitterionic Brushes in Diverse Conditions Induced by Shear Actions

期刊: MACROMOLECULES, 2021; 54 (12)

Polymer brushes are known to have excellent lubricity when grafted on surfaces in water. In this study, poly(2-(methacryloyloxy)-ethyl phosphorylcholi......

Effect of Ions on the Flow-Induced Crystallization of Poly(vinylidene fluoride)

期刊: MACROMOLECULES, 2021; 54 (8)

The flow-induced crystallization of poly(vinylidene fluoride) (PVDF)-ion composites in the presence of externally added ions was investigated by in si......

Influence of Side-Chain Length and Relative Rigidities of Backbone and Side Chains on Glass Formation of Branched Polymers

期刊: MACROMOLECULES, 2021; 54 (13)

Molecular branching is a common characteristic of both synthetic and natural polymers that plays a key role in determining their physical properties, ......

Water Intake and Ion Exchange in PEDOT:Tos Films upon Cyclic Voltammetry: Experimental and Molecular Dynamics Investigation

期刊: MACROMOLECULES, 2021; 54 (13)

Conductive polymer PEDOT:Tos (3,4-ethylenedioxythiophene doped with molecular tosylate) gained considerable attention in various devices for bioelectr......

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